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Updated: Jul 9, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

Published on: July 19, 2019

在从转移到pi-bonded导向分子CH3CN,CH3NC和CCl3CN中的电子转移中产生效应

Philip R Brooks1, Peter W Harland, Sean A Harris

  • 1Chemistry Department and Rice Quantum Institute, Rice University, Houston, Texas 77251, USA. brooks@python.rice.edu

Journal of the American Chemical Society
|November 29, 2007
PubMed
概括

涉及原子和烯的电子转移反应显示出不同的路径. 甲基化物化合物表现为侧向攻击,而三甲酸则倾向于在三甲基末端攻击,形成各种负离子.

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