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Updated: Jul 8, 2026

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
07:06

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis

Published on: February 16, 2020

催化不对称化2,3,5-三替代型烯的催化不对称化

Ryoichi Kuwano1, Manabu Kashiwabara, Masato Ohsumi

  • 1Department of Chemistry, Graduate School of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan. rkuwascc@mbox.nc.kyushu-u.ac.jp

Journal of the American Chemical Society
|December 25, 2007
PubMed
概括

这项研究引入了一种新型的催化剂,用于 pyrroles 的不对称化,实现高的 enantioselectivity. 这一突破使得能够有效地合成性烯酸衍生物和其他复杂的烯酸结构.

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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
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