在所有系统中,金属催化1,2-转移的多样化的迁移群体作为一种新范式,朝着密集的功能化异环循环发展

Alexander S Dudnik1, Anna W Sromek, Marina Rubina

  • 1Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, 4500 SES, M/C 111, Chicago, Illinois 60607-7061, USA.

概括

一种新的方法可以通过1,2-迁移和循环异构化有效合成替代的 furan 和 pyrrole. 这种多功能方法可以控制区域选择性,为合成化学制造出有价值的构建模块.

相关概念视频

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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[3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement

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