单壁碳纳米管的化使用聚胺试剂:结合实验和理论研究研究
Glen P Miller1, Jeremy Kintigh, Eunja Kim
1Department of Chemistry and Materials Science Program, University of New Hampshire, Durham, New Hampshire 03824, USA. glen.miller@unh.edu
Journal of the American Chemical Society
|January 29, 2008
概括
使用聚氨酸的单壁碳纳米管 (SWCNTs) 的化提高了它们的分散性. 原子在SWCNT上形成对齐的链条,增强稳定性和溶剂兼容性.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 纳米技术纳米技术
背景情况:
- 单壁碳纳米管 (SWCNTs) 具有独特的特性,但具有较差的可溶性.
- 控制SWCNT表面化学对于其应用和加工至关重要.
研究的目的:
- 通过使用高沸聚胺来研究SWCNTs的可逆化.
- 了解化SWCNT的吸附机制和结构变化.
主要方法:
- 结合了实验观测和初始计算的结合.
- 使用聚氨作为试剂进行化研究.
- 分析了吸附键的性质和几何形状.
主要成果:
- 在SWCNT上确定了的优先吸附点和几何形状.
- 确定了大约1 eV的原子重新排列的屏障,使扩散和链形成成为可能.
- 由于化,观察到SWCNT结构和稳定性的显著改变.
- 在化SWCNT中发现管间距离增加.
结论:
- 用聚氨酸化SWCNT可提高常见有机溶剂中的分散性.
- 轴对齐的链的形成增强了SWCNT的稳定性和管间间距.
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