染色体化增强可溶性二烯半导体的结晶和稳定性
Sankar Subramanian1, Sung Kyu Park, Sean R Parkin
1Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506, USA.
Journal of the American Chemical Society
|February 12, 2008
概括
部分化可溶性基衍生物显著提高了热和光稳定性. 这导致了p型半导体性能的提高,其中一种衍生品在晶体薄膜中实现了高孔流动性,另一种在独立的晶体中实现了高孔流动性.
科学领域:
- 有机电子学有机电子学
- 材料科学是一种材料科学.
- 半导体物理 半导体物理
背景情况:
- 可溶解的基衍生物是有前途的有机半导体.
- 提高这些材料的稳定性和电荷传输特性对于设备应用至关重要.
研究的目的:
- 为了研究部分化对可溶性二甲衍生物的稳定性和半导体性能的影响.
- 探索这些改性材料在有机电子设备中的潜力.
主要方法:
- 部分化炭基衍生物的合成.
- 材料稳定性的表征 (热和光-).
- 有机场效应晶体管 (OFET) 的制造和电气特性.
- 薄膜和单晶的结晶性评估.
主要成果:
- 与非化类似物相比,部分化显著提高了热和光稳定性.
- 三乙基替代衍生物形成了高度结晶的薄膜,孔流动性 > 1.0 cm(2) / V s.
- 三烯基衍生物形成了大型,高质量的晶体,具有高达0.1厘米的孔移动性.
结论:
- 部分化是一种有效的策略,可以提高可溶性基基p型半导体的稳定性.
- 这些材料显示出高性能有机电子应用的巨大潜力,包括晶体管.
- 形成高度结晶薄膜和大型单晶的能力为先进的设备制造开辟了道路.
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