有机n通道晶体管基于核心化烯碳酸二胺衍生物的有机n通道晶体管
R Thomas Weitz1, Konstantin Amsharov, Ute Zschieschang
1Max Planck Institute for Solid State Research, Heisenbergstrasse 1, 70569 Stuttgart, Germany. t.weitz@fkf.mpg.de
Journal of the American Chemical Society
|March 14, 2008
概括
功能化有机半导体使空气稳定的n通道晶体管成为可能. 研究人员发现了.
科学领域:
- 有机电子学有机电子学
- 材料科学是一种材料科学.
- 半导体物理 半导体物理
背景情况:
- 有机薄膜场效应晶体管 (OTFT) 对于灵活的电子产品至关重要.
- 开发稳定于空气的n通道有机半导体仍然是一个挑战.
- 功能化是提高空气稳定性的常见策略.
研究的目的:
- 合成和表征新型核心化烯碳酸二胺基 (PDI).
- 研究含替代剂对晶体管性能和空气稳定性的影响.
- 阐明在实现空气稳定的n通道运行中的作用.
主要方法:
- 合成五种功能化核心化PDI.
- 制造n通道有机薄膜场效应晶体管 (OTFT).
- 分子结构的表征,薄膜形态和设备在环境条件下的性能.
主要成果:
- 实现了空气稳定的n通道OTFT,载体流动性高达0.1cm2/Vs.
- 建立了分子设计,薄膜形态,沉积温度和设备特征之间的相关性.
- 观察到在空气稳定性中的作用不同于之前的假设.
结论:
- 的功能化可以导致空气稳定的n通道有机晶体管.
- 分子结构和加工条件显著影响设备性能.
- 对空气稳定性贡献的精确机制需要进一步研究.
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