相关实验视频
Updated: Jul 6, 2026

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Hyperpolarized Xenon for NMR and MRI Applications
Published on: September 6, 2012
一个具有两个贵重气体原子的小中性分子:HXeOXeH
Leonid Khriachtchev1, Karoliina Isokoski, Arik Cohen
1Laboratory of Physical Chemistry, P.O. Box 55, FIN-00014 University of Helsinki, Finland. Leonid.Khriachtchev@Helsinki.Fi
Journal of the American Chemical Society
|April 15, 2008
概括
研究人员使用红外光谱学识别了HXeOXeH,这是最小的中性分子,有两个贵重气体原子. 这一发现可能有助于创建氧链,解决"缺少的"问题.
科学领域:
- 贵族气体的化学结构
- 频谱学是一种光谱学.
- 量子化学是一种量子化学.
背景情况:
- 贵族气体化合物是罕见的,并且难以合成.
- 了解贵重气体的行为对于各种科学领域至关重要.
研究的目的:
- 为了识别和描述一种新型的贵重气体化合物.
- 探索贵重气体化合物的潜在应用.
主要方法:
- 红外 (IR) 光谱法用于识别.
- 在固体中对水进行紫外线光解,然后进行化.
- 广泛的量子化学计算支持了实验发现.
主要成果:
- 一个新的中性分子,HXeOXeH,含有两个贵重气体原子,已成功识别.
- HXeOXeH是已知的最小的中性分子,有两个贵重气体原子.
- 计算分析预测分解时会释放出8.3 eV的显著能量.
结论:
- 发现HXeOXeH代表了贵重气体化学的重大进步.
- 这种分子可能是合成异-氧链的前体.
- 这些发现可能有助于了解陆地"缺失的子"问题.
相关概念视频
Noble Gases
The elements in group 18 are noble gases (helium, neon, argon, krypton, xenon, and radon). They earned the name “noble” because they were assumed to be nonreactive since they have filled valence shells. In 1962, Dr. Neil Bartlett at the University of British Columbia proved this assumption to be false.
Exceptions to the Octet Rule
Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
VSEPR Theory and the Effect of Lone Pairs
Effect of Lone Pairs of Electrons on Molecule Geometry
Lewis Symbols and the Octet Rule
Chemical bonds are complex interactions between two or more atoms or ions, which reduce the potential energy of the molecule. Gilbert N. Lewis developed a model called the Lewis model that simplified the depiction of chemical bond formation and provided straightforward explanations for the chemical bonds seen in most common compounds.
Lewis Structures of Molecular Compounds and Polyatomic Ions
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
Ionic Bonding and Electron Transfer
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.

