D3h C78 (金属) 富勒烯的化学反应性:由Sc3N封装诱导的区域选择性变化

Sílvia Osuna1, Marcel Swart, Josep M Campanera

  • 1Institut de Química Computacional and Departament de Química, Universitat de Girona, Campus Montilivi, 17071 Girona, Catalonia, Spain.

概括

在富勒烯中封装一个金属化物团,显著改变了它的外体反应性. 由于反应部位发生变化,Diels-Alder对内体金属烯的反应与自由烯相比产生了不同的产物.

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