水性酸盐在高压下融化,在高压下融化
Mainak Mookherjee1, Lars Stixrude, Bijaya Karki
1Department of Geology and Geophysics, Yale University, New Haven, Connecticut 06511, USA.
Nature
|April 25, 2008
概括
水水水水水,这是一个很好的方法.
科学领域:
- 地质化学 地质化学
- 高压物理学的高压物理
- 材料科学是一种材料科学.
背景情况:
- 水性酸盐融的行为和地球地幔中的水溶性是鲜为人知的.
- 水在较低的压力下显著影响化的特性,如密度,粘度和电导率.
研究的目的:
- 为了研究水性MgSiO3在高压下融化的结构和特性.
- 为了确定水的物种化和酸盐融化的混合性,跨地幔压力.
主要方法:
- 使用了第一原则分子动力学模拟.
- 模拟涵盖了高达地球地幔状态 (136 GPa) 的压力.
主要成果:
- 水的物种化从分子/基转移到扩展结构,压力增加.
- 在大多数地幔压力下观察到水和酸盐融的完全混合性.
- 在上层地幔底部浮力稳定的融物中,含有~3重%的水.
结论:
- 高压从根本上改变了水的物种化,并促进了酸融化的混合性.
- 预计在上层地幔底部的水性融化 (~3重%的水) 可以通过电磁探测检测到.
更多相关视频
06:54Preparing Silica Aerogel Monoliths via a Rapid Supercritical Extraction Method
Published on: February 28, 2014
21.0K
11:50Metal-silicate Partitioning at High Pressure and Temperature: Experimental Methods and a Protocol to Suppress Highly Siderophile Element Inclusions
Published on: June 13, 2015
12.0K
相关概念视频
Phase Diagrams
45.6K
A phase diagram combines plots of pressure versus temperature for the liquid-gas, solid-liquid, and solid-gas phase-transition equilibria of a substance. These diagrams indicate the physical states that exist under specific conditions of pressure and temperature and also provide the pressure dependence of the phase-transition temperatures (melting points, sublimation points, boiling points). Regions or areas labeled solid, liquid, and gas represent single phases, while lines or curves represent...
45.6K
Washing, Drying, and Ignition of Precipitates
5.8K
After filtration, the precipitate is washed to remove coprecipitated impurities and any remaining mother liquor. Colloidal precipitates, such as silver chloride, are washed with an electrolyte (such as dilute nitric acid) to prevent the peptization of the precipitate. In the case of slightly soluble precipitates, the wash solution contains a common ion to reduce solubility. Lead sulfate, which is slightly soluble in water, is washed with dilute sulfuric acid. Similarly, wash solutions may be...
5.8K
Hydration of Cement
2.0K
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
2.0K
Strength and Heat of Hydration
962
The hydration of cement is an exothermic reaction in which heat is generated as cement hydrates. This heat of hydration is critical to cement's strength development. The rate at which this heat is generated affects the temperature rise, with a majority of the heat being released early in the hydration process, half within the first three days, and about 75% within the first week.
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
962
