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溶剂对碳化合物系统间交叉率的影响

Jin Wang1, Jacek Kubicki, Huolei Peng

  • 1Department of Chemistry, The Ohio State University, 100 West 18th Avenue, Columbus, Ohio 43210, USA.

Journal of the American Chemical Society
|April 25, 2008
PubMed
概括

协调溶剂会影响碳素系统间交叉 (ISC) 速率. 特定的溶剂相互作用,而不仅仅是极性,通过稳定单片碳素来影响ISC,似乎违反了无辐射过渡的黄金规则.

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