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Updated: Jul 5, 2026

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
08:09

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Published on: May 9, 2014

乙醇/111) 自组装单层含有黄金的原子:扫描道显微镜在与原子反应之前和之后

Natalie A Kautz1, S Alex Kandel

  • 1Department of Chemistry and Biochemistry, University of Notre Dame, 251 Nieuwland Science Hall, Notre Dame, Indiana 46556, USA.

Journal of the American Chemical Society
|May 8, 2008
PubMed
概括

黄金表面上的自组合的乙醇含有黄金的原子. 移除单层揭示了这些天,表明重建的黄金表面和复杂的硫黄键.

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Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride01:26

Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride

Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...