ShibasakiLi3(THF) n(BINOLate) 3Ln.

Alfred J Wooten1, Patrick J Carroll, Patrick J Walsh

  • 1P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104-6323, USA.

概括

这项研究描述了新型异金属易斯酸的特征,揭示了基质与类中心的结合如何影响不对称的催化. 研究结果表明,胺中心可能不会对双酸基质进行合,从而影响催化反应中的酶选择性.

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