三重氧同位素证据表明,在新新生代冰川化之后,二氧化碳水平升高
Huiming Bao1, J R Lyons, Chuanming Zhou
1Department of Geology and Geophysics, E235 Howe-Russell Geoscience Complex, Louisiana State University, Baton Rouge, Louisiana 70803, USA. bao@lsu.edu
Nature
|May 24, 2008
概括
古老的硫酸盐 在古代的硫酸盐.
科学领域:
- 地质化学 地质化学
- 古气候学 古气候学
- 地球系统科学 地球系统科学
背景情况:
- 大气组成是地球历史的关键.
- 直接的大气记录很少.
- 地质学家使用间接方法来重建过去的大气层.
研究的目的:
- 使用新型同位素代理来重建过去的大气组成.
- 为了研究大气氧气,二氧化碳和臭氧在地质时间上的联系.
- 测试关于新新生代气候事件的假设.
主要方法:
- 在古老的硫酸盐 (蒸发石和石) 中分析三氧同位素组成 (17O异常).
- 利用硫酸盐的氧-17同位素异常作为大气氧的代理.
- 通过光化学模型将大气中的氧气变化与二氧化碳水平联系起来.
主要成果:
- 在过去的7.5亿年中观察到硫酸盐中的可变负氧-17同位素异常.
- 这些异常与过去的大气氧气水平相关,并推断出二氧化碳部分压力 (P(CO2).
- 与晚期相比,早期坎布里亚纪有显著更高的二氧化碳的证据.
- 马里诺巴里特中明显的负17O异常峰值表明,在新新生代冰川化之后,P(CO2) 达到峰值.
结论:
- 硫酸盐中的三氧同位素为过去大气组成提供了一个新的代理.
- 推断的P(CO2) 趋势与现有模型保持一致,并支持高的早期坎布里亚二氧化碳水平.
- 马里诺异常支持"雪球地球"假设或冰期后大量的甲释放.
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