具有相当大的孔移动性和空气稳定性的半导体纤维聚合物的合成,表征和晶体管响应. 实验和理论的实验和理论
Gang Lu1, Hakan Usta, Chad Risko
1Department of Chemistry and the Materials Research Center, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
Journal of the American Chemical Society
|May 29, 2008
概括
新的基于dithienosilol和dibenzosilol的半导体聚合物提供了空气稳定,可溶液处理的高孔移动性的p通道薄膜晶体管 (TFT),从而推进了印刷电子.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 有机电子 有机电子
背景情况:
- 开发p通道半导体聚合物对于推进印刷电子技术至关重要.
- 关键的挑战包括实现高孔流动性,解决方案可加工性和空气稳定性.
- 现有的材料,如区域常规的聚3-基烯 (P3HT),在空气稳定性方面存在局限性.
研究的目的:
- 为了合成和描述新的dithienosilole和dibenzosilole基聚合物.
- 调查这些芯对聚合物特性和电荷运输的影响.
- 开发稳定于空气的高性能有机薄膜晶体管 (OTFT).
主要方法:
- 同聚合物 (TS6,BS8) 和共聚物 (TS6T1,TS6T2,BS8T1,BS8T2) 的合成.
- 合成聚合物的完整特征.
- 在环境条件下制造和测试空气稳定的薄膜晶体管 (TFT).
- 密度函数理论 (DFT) 计算用于理论见解.
主要成果:
- 经过证明的空气稳定TFT,孔移动度高达0.08cm2/V·s.
- 实现了低开启电压和高电流开/关比 (> 106).
- 未封装的TFT显示出显著的空气稳定性,超过了基于P3HT的设备.
- 确定了孔注射屏障,TFT性能和薄膜形态之间的直接相关性.
结论:
- 狄西和二西芯显著提高了电子应用的聚合物特性.
- 新的聚合物可以开发出强大的,稳定的,可处理溶液的有机电子产品.
- 这些发现代表了化学操纵聚合物中电荷传输的重要一步.
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