在使用[(dippe) NiH]2在2-甲基-3-丁中竞争性裂解C-CN和C-H键时的溶剂效应和激活参数

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Brett D Swartz1, Nicole M Reinartz, William W Brennessel

  • 1Department of Chemistry, University of Rochester, Rochester, New York 14627, USA.

Journal of the American Chemical Society
|June 11, 2008
PubMed
概括

溶剂的极性决定了化与2-甲基-3-丁二 (2M3BN) 的反应性. 极性溶剂有利于C-H激活,而非极性溶剂促进C-C裂变,影响反应途径和产品比率.

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