一种有机敏化剂,配有合的dithienothiophene单元,用于高效和稳定的染料敏化太阳能电池
Hao Qin1, Sophie Wenger, Mingfei Xu
1State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
Journal of the American Chemical Society
|June 28, 2008
概括
研究人员开发了一种高摩尔灭绝系数有机敏化剂,用于高效的染料敏化太阳能电池 (DSC). 这一创新,结合离子液体电解质,产生稳定,高性能电池,适合灵活的电子.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 太阳能光伏发电是如何实现的
背景情况:
- 染料敏感化太阳能电池 (DSC) 提供了低成本可再生能源的潜力.
- 提高DSC的效率和稳定性对于商业可行性至关重要.
- 有机敏感剂是影响太阳能电池性能的关键组成部分.
研究的目的:
- 开发一种具有高摩尔灭绝系数的新型有机敏感剂.
- 为了提高染料敏感太阳能电池的效率和长期稳定性.
- 为了评估DSC的性能,使用无溶剂的离子液体电解质.
主要方法:
- 一种具有高摩尔灭绝系数的新型有机敏感剂的合成.
- 制造染料敏感的太阳能电池,其中包含了新的敏感剂.
- 使用无溶剂的离子液体电解质测试电池性能.
- 评估设备在联合热和光浸泡压力下的稳定性.
主要成果:
- 开发的有机敏感剂表现出高的摩尔灭绝系数.
- 染料敏感的太阳能电池实现了大约7%的功率转换效率.
- 制造的电池在双热和光浸泡压力下表现出极好的稳定性.
- 使用无溶剂的离子液体电解质有助于设备的稳定性.
结论:
- 这种新型有机敏化剂对高效率的DSCs非常有效.
- 敏感剂和离子液体电解质的组合导致了强大而稳定的太阳能电池.
- 这一进步对生产灵活,低成本和轻量级的DSC有重大影响.
相关概念视频
Aryldiazonium Salts to Azo Dyes: Diazo Coupling
The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.
Photochemical Electrocyclic Reactions: Stereochemistry
The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
Selection Rules: Photochemical Activation


