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Updated: Jul 1, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

使用离子Cp*Rh(III) 催化剂对循环胺的不对称化

Chaoqun Li1, Jianliang Xiao

  • 1Department of Chemistry, Liverpool Centre for Materials and Catalysis, University of Liverpool, Liverpool L69 7ZD, UK.

Journal of the American Chemical Society
|September 12, 2008
PubMed
概括

具有庞大的对抗离子的阴离子催化剂在循环 imines 的不对称化过程中达到高的 enantioselectivity. 这种方法有效地产生有价值的生物活性四二诺和四二-β-醇,其纯度极佳.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Electrophilic Addition to Alkynes: Halogenation

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