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Updated: Jun 29, 2026

Fabrication of Large-area Free-standing Ultrathin Polymer Films
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Fabrication of Large-area Free-standing Ultrathin Polymer Films

Published on: June 3, 2015

在PdAu表面合金上合成乙乙酸乙烯的模板效应:密度功能理论研究研究

Mónica García-Mota1, Núria López

  • 1Institute of Chemical Research of Catalonia, ICIQ, Avgda. Països Catalans 16, 43007 Tarragona, Spain.

Journal of the American Chemical Society
|October 9, 2008
PubMed
概括

密度函数理论揭示了用于合成乙乙酸乙烯的黄金表面上的最佳二元配置. 最好的催化剂设计平衡了反应剂吸附和低反应障碍,以获得高效的催化活性.

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Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics10:52

Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics

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Acetals and Thioacetals as Protecting Groups for Aldehydes and Ketones

Acetals are formed by reacting two equivalents of alcohol with carbonyl compounds like aldehydes or ketones. Acetals are unaffected by bases, nucleophiles, oxidizing agents, and reducing agents. They serve as protecting groups for aldehydes and ketones. Acetals can be easily formed and also easily removed via mild acid hydrolysis.
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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
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