铁二氧化物:用于高流动性n通道晶体管半导体的最小核心
Qingdong Zheng1, Jia Huang, Amy Sarjeant
1Department of Materials Science and Engineering, The Johns Hopkins University, 103 Maryland Hall, 3400 North Charles Street, Baltimore, Maryland 21218, USA.
Journal of the American Chemical Society
|October 10, 2008
概括
合成了三种新的铁二化物,产生了高性能有机半导体薄膜. 这些材料表现出优异的充电流动性和电子设备的高开/关比.
科学领域:
- 有机化学 有机化学
- 材料科学是一种材料科学.
- 半导体物理 半导体物理
背景情况:
- 铁二化物是有机化合物的一类,在电子领域具有潜在的应用.
- 开发高性能有机半导体对于下一代电子设备至关重要.
研究的目的:
- 为了合成新型的 pyromellitic diimide 衍生物.
- 评估由这些新化合物衍生的薄膜的电子特性.
主要方法:
- 烧二化物和各种氨基之间的常规合成反应.
- 从合成的铁二化物制造薄膜.
- 在n频道设备中,电荷载体移动性和开/关比的表征.
主要成果:
- 通过合成三种铁二胺衍生物,获得了高产量.
- 有机半导体薄膜表现出电荷载体移动性高达0.079cm2/{Vs}.
- 实现了非常高的开/关比率,在n频道设备中达到100万.
结论:
- 合成的 pyromellitic diimides 是有机电子学有前途的材料.
- 高流动性和开/关比表明了高效的n通道有机场效应晶体管的潜力.
- 这项工作有助于提高高性能有机半导体材料的进步.
更多相关视频
12:07Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
Published on: April 1, 2013
10:31Plasma-assisted Molecular Beam Epitaxy of N-polar InAlN-barrier High-electron-mobility Transistors
Published on: November 24, 2016
相关概念视频
Types of Semiconductors
Intrinsic semiconductors are highly pure materials with no impurities. At absolute zero, these semiconductors behave as perfect insulators because all the valence electrons are bound, and the conduction band is empty, disallowing electrical conduction. The Fermi level is a concept used to describe the probability of occupancy of energy levels by electrons at thermal equilibrium. In intrinsic semiconductors, the Fermi level is positioned at the midpoint of the energy gap at absolute zero. When...
Metal-Semiconductor Junctions
The contact of metal and semiconductor can lead to the formation of a junction with either Schottky or Ohmic behavior.
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The semiconductor's...
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The semiconductor's...
Semiconductors
There is variation in the electrical conductivity of materials - metals, semiconductors, and insulators that are showcased with the help of the energy band diagrams.
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
P-N junction
A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
Biasing of P-N Junction
The operation of a p-n junction diode involves various biasing conditions, including forward bias, reverse bias, and equilibrium.
In equilibrium, no external voltage is applied across the p-n junction. The depletion region is formed at the junction interface due to the diffusion of carriers, which leaves behind charged dopants, acceptors on the p-side, and donors on the n-side. These immobile charges create an electric field that prevents further diffusion of carriers. The related energy band...
In equilibrium, no external voltage is applied across the p-n junction. The depletion region is formed at the junction interface due to the diffusion of carriers, which leaves behind charged dopants, acceptors on the p-side, and donors on the n-side. These immobile charges create an electric field that prevents further diffusion of carriers. The related energy band...
Schottky Barrier Diode
Schottky barrier diodes are specialized semiconductor devices characterized by their unique construction. This construction involves combining a metal layer with a moderately doped n-type semiconductor material. This combination leads to the formation of a Schottky barrier, a pivotal element that defines the diode's operational characteristics. The core functionality of Schottky barrier diodes is their capacity to allow current to flow in only one direction due to their distinctive...
