在功能模型中,aza-和oxadithiolates可能是[FeFe]-基酶的质子继电器

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Updated: Jun 27, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

Bryan E Barton1, Matthew T Olsen, Thomas B Rauchfuss

  • 1School of Chemical Sciences, University of Illinois, Urbana, Illinois 61801, USA.

Journal of the American Chemical Society
|December 5, 2008
PubMed
概括

在[FeFe]酶模型中的阿扎迪酸盐和氧基酸盐辅因子提高了质子转移速率. 这些含有异原子的共因子作为质子继电器,使得高效的化物形成和进化,特别是从弱酸.

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