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Updated: Jun 27, 2026

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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通过O2激活通过一个宏环二铜 (I) 复合体,完成西格玛*分子内芳氧化过程的完整机制

Albert Poater1, Xavi Ribas, Antoni Llobet

  • 1Modeling Laboratory for Nanostructures and Catalysis (MoLNaC), Dipartimento di Chimica, Universita degli Studi di Salerno, via Ponte don Melillo, Fisciano (SA), 84084, Italy.

Journal of the American Chemical Society
|December 6, 2008
PubMed
概括

本研究详细介绍了使用二铜I) 复合体进行分子内芳香氧化的机制. 它揭示了氧激活中的关键中间体,如超氧和过氧物种,指导了未来的催化剂设计.

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