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桥梁金属有机框架的纳米结构和溢出

Cheng-Si Tsao1, Ming-Sheng Yu, Cheng-Yu Wang

  • 1Institute of Nuclear Energy Research, Longtan 32546, Taiwan. cstsao@iner.gov.tw

Journal of the American Chemical Society
|January 15, 2009
PubMed
概括

金属有机框架 (MOF) 在室温下通过桥梁溢出吸附. 不完美的格子缺陷和3D孔隙网络是吸收的关键,而不仅仅是表面积或微孔.

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A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...