脉冲添加环开通元解聚合:同聚合物和区块共聚物的催化剂经济合成

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Updated: Jun 25, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

Published on: December 16, 2022

John B Matson1, Scott C Virgil, Robert H Grubbs

  • 1Center for Catalysis and Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|February 14, 2009
PubMed
概括

脉冲添加环开通转化聚合 (PA-ROMP) 能够控制聚合物的合成和阻断聚合物,具有狭窄的分子量分布. 这种新的方法使用链传递剂来再生启动器,允许从单一催化剂进行多个聚合周期.

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