在azafullerene封装单壁碳纳米管FET设备中的光开关
Yongfeng Li1, Toshiro Kaneko, Jing Kong
1Department of Electronic Engineering, Tohoku University, Sendai 980-8579, Japan. yfli@plasma.ecei.tohoku.ac.jp
Journal of the American Chemical Society
|February 24, 2009
概括
单壁碳纳米管 (SWNTs) 内的Az富勒烯分子创建了对紫外线敏感的场效应晶体管 (FET) 设备. 这种光诱导的电子转移会导致源-排水电流的减少,表明依赖光的光交换效应.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 物理化学 物理化学
背景情况:
- 单壁碳纳米管 (SWNTs) 正在探索电子应用.
- 阿扎富勒伦是具有独特电子性质的新型碳基.
- 光响应分子系统对于光电子设备至关重要.
研究的目的:
- 为了研究C(59) N@SWNTs.的光诱导电传特性.
- 评估纳米管场效应晶体管 (FET) 设备对光暴露的敏感性.
- 了解这些混合纳米结构中的光交换机制.
主要方法:
- 使用C(59) N@SWNTs的场效应晶体管 (FET) 设备的制造.
- 在不同的光波长下测量源-排水电流.
- 对光诱导电子转移现象的分析.
主要成果:
- 集成到FET设备中的N@SWNT对紫外线光有很高的敏感性.
- 在暴露于光线时观察到源-排水电流的减少,这表明光交换.
- 光交换效应取决于波长,在480nm以上减弱.
结论:
- 在SWNTs中的azafullerene分子使光敏感纳米管FETs成为可能.
- 在C(59) N@SWNTs内部的光诱导电子转移是观察到的光交换的原因.
- 的电子结构促进了光诱导的电荷转移,使其对特定波长敏感.
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