相关实验视频

Updated: Jun 25, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

在复合体中的C-C减小消除,以及合添加剂的作用. 由实验支持的DFT研究

Martín Pérez-Rodríguez1, Ataualpa A C Braga, Max Garcia-Melchor

  • 1Departamento de Química Organica, Facultad de Química, Universidade de Vigo, Lagoas-Marcosende s/n, 36310 Vigo, Galicia, Spain.

Journal of the American Chemical Society
|February 24, 2009
PubMed
概括

这项研究使用DFT来研究在催化过程中的还原性淘汰. 它发现添加剂显著改变反应途径和激活能量,并没有为这些关键的催化步骤揭示任何单一的普遍机制.

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