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六个一氧化碳由一个ditantalium化物复合体的减少合

Takahito Watanabe1, Yutaka Ishida, Tsukasa Matsuo

  • 1Department of Chemistry, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8551, Japan.

Journal of the American Chemical Society
|February 27, 2009
PubMed
概括

一个ditantalium化物复合物催化了六个一氧化碳 (CO) 分子的合,形成一个八性C(6) O(6) 集群. 这种反应涉及八个电子的减少,形成一个独特的金属-碳-氧结构.

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