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Updated: Jun 24, 2026

Photoelectron Imaging of Anions Illustrated by 310 Nm Detachment of F−
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Photoelectron Imaging of Anions Illustrated by 310 Nm Detachment of F−

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使用具有可变电子亲和度的标签探测电子捕获和电子转移解离的机制

Chang Ho Sohn1, Cheol K Chung, Sheng Yin

  • 1Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|April 1, 2009
PubMed
概括

研究了电子捕获解离 (ECD) 和电子转移解离 (ETD) 机制,使用电子亲和力 (EA) 调节的. 高EA电子捕食者通过质子转移形成稳定的基质中间体来抑制碎片化,从而改变标准的ECD/ETD路径.

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