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响应刺激的液体大理石.
Damien Dupin1, Steven P Armes, Syuji Fujii
1Department of Chemistry, Dainton Building, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK.
Journal of the American Chemical Society
|April 2, 2009
概括
这项研究表明,使用pH响应的聚烯乳颗粒,可以制造出坚固的液体大理石. 这些新型的液体大理石在空气/水界面上是稳定的,可以用酸可控地摧毁.
科学领域:
- 材料科学 材料科学 材料科学
- 合体和表面化学
背景情况:
- 液体大理石通常是使用高度疏水性颗粒形成的.
- 现有的方法依赖于专门的非水性颗粒制剂.
研究的目的:
- 开发一种新的方法,使用绝缘稳定聚烯乳制造液体大理石.
- 为了研究这些新形成的液体大理石的pH反应性质.
主要方法:
- 使用水性乳液聚合来合成聚烯乳颗粒.
- 一种烯功能化的聚二乙氨基乙烯甲基酸) 宏观农药被用作反应性固体稳定剂.
- 稳定剂的pH取决于溶解度被利用了液体大理石的形成和稳定性.
主要成果:
- 强大的毫米大小的液体大理石成功地使用合成的聚乙烯乳制备.
- 液体大理石在空气/水界面上表现出稳定性,这是由于脱质,疏水稳定剂链.
- 液体大理石表现出pH响应的行为,在添加酸时被破坏.
结论:
- 立体稳定聚烯乳为液体大理石制备提供了可行的替代方案.
- 稳定剂的pH反应性使液体大理石的稳定性和破坏性得以控制.
- 这项工作扩大了创建功能性和响应性液体大理石系统的工具包.


