由于在天然气田中占主导地位的二氧化碳 (CO2) 沉没,溶性在形成水中被困
Stuart M V Gilfillan1, Barbara Sherwood Lollar, Greg Holland
1School of Earth, Atmospheric and Environmental Sciences, The University of Manchester, Oxford Road, Manchester M13 9PL, UK. stuart.gilfillan@ed.ac.uk
Nature
|April 3, 2009
概括
二氧化碳 (CO2) 的地质储存依赖于了解CO2的命运. 天然气田显示,二氧化碳 (CO2) 主要溶于形成水中,矿物沉起了较小的作用.
科学领域:
- 地质化学 地质化学
- 环境科学 环境科学
- 地质地质地质地质地质地
背景情况:
- 将二氧化碳 (CO2) 注入深层地质层是工业碳捕获和储存的关键策略.
- 评估注入的CO2的长期命运对于场地设计和安全建模至关重要,但很难从短期观察中确定.
研究的目的:
- 确定和量化CO2从天然气田中的流体相中去除CO2的主要机制.
- 使用这些自然类型来预测人类产生的二氧化碳 (CO2) 储存在千年时间尺度上的长期行为.
主要方法:
- 在北美,中国和欧洲的九个天然气田中分析了贵重气体和碳同位素.
- 调查自然占主导地位的CO2阶段的田地,以模拟地质储存条件.
主要成果:
- 在九个研究领域中的七个领域 (酸盐或碳酸盐石质学),CO2溶解在形成水中 (pH5-5.8) 是主要的去除机制.
- 在两个状矿场中,碳酸盐矿物沉最多占二氧化碳 (CO2) 损失的18%,这表明它是一种轻微的捕获机制.
结论:
- 地质矿物固定是研究的天然气田中二氧化碳的轻微捕获机制.
- 在类似的地质系统中,人为CO2存储的长期模型应该优先考虑溶解CO2在形成水中的潜在流动性.
更多相关视频
相关概念视频
Entropy and Solvation
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ ≥ 15); an...
Gas Solubility
Gas solubility in liquids forms liquid-gas solutions, such as soft drinks, where carbon dioxide is dissolved in water, and the ocean, where the solubility of oxygen and carbon dioxide supports marine life. The ability of oceans to dissolve gases impacts weather conditions in the troposphere.However, gas-liquid interactions vary. For instance, hydrogen chloride gas is highly soluble in water, while oxygen's solubility is much lower. Because these solutions are non-ideal, Raoult’s law, which...
Physical Properties Affecting Solubility
Solutions of Gases in Liquids
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
Solubility
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules, atoms, and/or ions)...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules, atoms, and/or ions)...
Chemical and Solubility Equilibria
The free energy change associated with dissolving a solute in a liter of solvent is called the free energy of a solution, ΔGsolution. The overall ΔGsolution is expressed as the balance of ΔGinteraction against the always-favorable free-energy of mixing, ΔGmixing. Solution formation is favorable if ΔGsolution is less than zero, whereas it is unfavorable if ΔGsolution is greater than zero. In short, for a solution to form and complete dissolution to take place, the Gibbs energy change must be...
Solution Formation
There is no one solvent that can dissolve every type of solute. Some substances that readily dissolve in a certain solvent might be insoluble in a different solvent. A simple way to predict which substances dissolve in which solvent is the phrase "like dissolves like". This means that polar substances, such as salt and sugar, dissolve in a polar substance like water. In contrast, non-polar substances are more soluble in non-polar solvents such as carbon tetrachloride.
This selective solubility...
This selective solubility...


