在聚合物电解质燃料电池中,具有改善氧降低活性的铁基催化剂
Michel Lefèvre1, Eric Proietti, Frédéric Jaouen
1Institut National de la Recherche Scientifique, Energie, Matériaux et Télécommunication, Varennes, Québec J3X 1S2, Canada.
概括
研究人员为燃料电池开发了先进的铁基催化剂,显著增加了活性位点. 这些催化剂现在与金性能竞争,为清洁能源应用提供了一个有前途的替代方案.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
背景情况:
- 基于铁的催化剂在聚合物电解质膜燃料电池中的氧气减少方面不如具有竞争力,这是由于活性位点密度低.
- 为推进燃料电池技术,开发高效且具有成本效益的替代品至关重要.
研究的目的:
- 为了提高氧降解反应 (ORR) 的铁基催化剂的活性位点密度.
- 为了实现与聚合物电解质膜燃料电池 (PEMFCs) 中的白金催化剂相当的性能.
主要方法:
- 合成的微孔碳支持铁基催化剂.
- 使用了一种合成途径,涉及球磨法氨酸和铁酸与碳支,随后是双热解 (然后氨).
- 描述了催化剂结构,重点关注石墨微孔内由酸协调的铁离子.
主要成果:
- 优化的合成方法显著增加了活性位点的密度.
- 由此产生的铁基电催化剂在0.4毫克Pt/cm2的负载下实现了与类催化剂相当的电流密度.
- 催化剂在电池电压大于或等于0.9V时表现出高性能.
结论:
- 开发的基于铁的催化剂在PEMFCs中的氧降解反应中表现出具有竞争力的性能.
- 合成策略有效地提高了活性位点密度,解决了以前铁催化剂的关键局限性.
- 这一进步为燃料电池应用中金提供了一个可行的,潜在的低成本替代品.
相关概念视频
Batteries and Fuel Cells
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
Catalysis
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
Catalysis
Catalysis influences the rate of chemical reactions by providing an alternative reaction pathway with lower activation energy. A catalyst speeds up a reaction, but it is not consumed during the process. The fundamental principle of catalysis is the ability of a catalyst to alter the reaction mechanism, often introducing a more efficient pathway than the uncatalyzed process.In a catalyzed reaction, the catalyst participates directly in the reaction mechanism. It interacts with reactants to form...
Heterogeneous Catalysis
Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
Olefin Metathesis Polymerization: Overview
Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
Microbial Fuel Cells
Microbial fuel cells (MFCs) are bioelectrochemical devices that generate electricity by exploiting the metabolic processes of electrogenic bacteria. These systems provide a renewable energy source and serve as an innovative method for treating organic waste, such as wastewater.A typical MFC consists of two chambers: an anoxic (oxygen-free) compartment that houses the bacteria and an oxic (oxygen-rich) compartment that contains oxygen as the terminal electron acceptor. Many MFCs use proton...


