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相关概念视频

Heterogeneous Catalysis01:22

Heterogeneous Catalysis

Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
Catalysis01:27

Catalysis

Catalysis influences the rate of chemical reactions by providing an alternative reaction pathway with lower activation energy. A catalyst speeds up a reaction, but it is not consumed during the process. The fundamental principle of catalysis is the ability of a catalyst to alter the reaction mechanism, often introducing a more efficient pathway than the uncatalyzed process.In a catalyzed reaction, the catalyst participates directly in the reaction mechanism. It interacts with reactants to form...
Catalysis02:50

Catalysis

The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the surface of...
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.

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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
12:08

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金阵列催化剂的形状依赖活性.

Vladimir Komanicky1, Hakim Iddir, Kee-Chul Chang

  • 1Safarik University, Faculty of Sciences and, Institute of Experimental Physics, SAS, Kosice 04154, Slovakia. vladimir.komanicky@upjs.sk

Journal of the American Chemical Society
|April 8, 2009
PubMed
概括
此摘要是机器生成的。

我们在酸基板上制造了酸催化剂纳米粒子. 它们的特定的侧面安排显著影响氧降解反应活性,这对燃料电池至关重要.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 催化剂是一种催化剂.

背景情况:

  • 纳米颗粒是重要的催化剂,特别是在燃料电池中的氧降解反应中.
  • 控制纳米粒子形态和基质相互作用是提高催化性能的关键.
  • 了解特定方面活动对于设计高效的催化剂至关重要.

研究的目的:

  • 制造和表征有序的催化剂纳米粒子阵列,具有受控的形态.
  • 为了将微观结构特征与宏观催化活性相关联.
  • 为了研究不同晶体学方面在氧降解反应中的作用.

主要方法:

  • 在基酸基板上纳米颗粒的长轴生长 ((111), (100), (110)).
  • 利用电子束光刻技术精确制造纳米粒子阵列.
  • 对氧降解反应的催化活性进行电化学评估.

主要成果:

  • 数以百万计的形态相同的纳米粒子已经成功地在有序的阵列中生产出来.
  • 催化活性因 (111) 面和 (100) 面的不同比率而有所不同.
  • 增加的活性表明不同氧 afinities 的面体之间的合作作用.

结论:

  • 面积 (100) 面的表面积是催化剂减氧性能的一个关键因素.
  • 催化剂的方面工程为提高燃料电池效率提供了一条途径.
  • 不同晶体面之间的合作相互作用增强了催化反应性.