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在硫化纳米棒中的阴离子交换过程中的选择性面反应性

Bryce Sadtler1, Denis O Demchenko, Haimei Zheng

  • 1Department of Chemistry, University of California, Berkeley, California 94720, USA.

Journal of the American Chemical Society
|April 9, 2009
PubMed
概括

阴离子交换反应中的面选择性是控制纳米晶异构形态学的关键. 铜在硫化纳米棒中的交换优先发生在末端,产生独特的结构,与以前的白银不同.

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...