产生和捕获一个终端酸胺基复合物的生成和捕获
Matthew P Duffy1, François Mathey
1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371.
Journal of the American Chemical Society
|May 14, 2009
概括
一种新型的化胺复合物被合成并与不和化合物反应. 这种反应产生了各种氨酸复合物,包括 хлорофосфирен, хлорофосфиран和 хлорофосфолен.
科学领域:
- 有机金属化学 有机金属化学
- 酸盐化学 酸盐化学
- 协调化学 协调化学
背景情况:
- 碳基复合物是有机金属合成中的多功能前体.
- 斯菲尼丁复合物是高度反应性的中间体.
- 胺复合物的合成和反应性对于开发新的含化合物至关重要.
研究的目的:
- 为了合成一种新型的 () 五碳复合物. 复合物.
- 为了研究这种素复合物的与各种不和基质的反应性.
- 为了描述由此产生的含有机金属复合物.
主要方法:
- 合成一个7-酸盐-博纳迪因复合物中间体.
- 在60-70°C的温度下热生成 (酸) 五碳酸复合物.
- 氨基复合物的与基因,基因和结合基因的反应.
- 使用光谱方法 (隐含) 进行产品的表征.
主要成果:
- 在现场成功生成了 (酸胺) 五碳酸复合物.
- 素复合物与基因,基因和结合基因发生反应.
- 这些反应产生了相应的酸,酸和酸的复合物.
- 在与环合的反应中获得了单个异构体.
结论:
- 由此产生的 () 碳酸复合物是一种能够经历循环添加反应的活性物种.
- 这种方法为新型有机化合物提供了一条通往中心的路线.
- 反应的立体化学结果可以控制,循环烯的单个异构体形成证明了这一点.
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