一个多功能3D铁电和NLO活性多孔金属有机框架
Zhengang Guo1, Rong Cao, Xin Wang
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, PR China.
Journal of the American Chemical Society
|May 21, 2009
概括
研究人员使用四碳酸盐链接剂和离子创建了一个性多孔金属有机框架. 这种新型材料具有铁电和非线性光学特性.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
- 物理 物理学 物理
背景情况:
- 金属有机框架 (MOF) 是由金属离子和有机连接物构成的晶体材料.
- 在MOFs中的性对于在enantioselective催化和性分离中的应用至关重要.
- 铁电和非线性光学 (NLO) 属性对于先进的电子和光子设备是可取的.
研究的目的:
- 为了合成一种新的性多孔金属有机框架.
- 研究合成的MOF的铁电和第二阶非线性光学 (NLO) 特性.
主要方法:
- 使用四碳酸盐有机连接剂和Zn (II) 离子进行溶热合成.
- 通过X射线衍射测定状结构的确定.
- 铁电财产测量. 铁电财产测量.
- 对于NLO属性评估的第二和生成 (SHG) 实验.
主要成果:
- 成功组装了一种性多孔金属有机框架.
- 对自发电极化的观察,证实了铁电的行为.
- 显著的第二阶非线性光学响应的证明.
结论:
- 合成的性MOF具有铁电和NLO两种特性.
- 这种材料代表了多功能多孔材料的新平台.
- 在奇拉电子和光子学中的潜在应用.
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