BaNbO(IO3)5:一种具有非常大的SHG反应的新极性材料
Chuan-Fu Sun1, Chun-Li Hu, Xiang Xu
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China.
Journal of the American Chemical Society
|June 24, 2009
概括
一种新的非线性光学材料,酸酸 (BaNbO (((IO ((3)) ((5)),显示出强烈的第二波生成 (SHG) 响应. 这种材料具有热稳定性和相位匹配性,使其对光学应用具有前景.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 非线性光学是非线性光学.
背景情况:
- 对于非线性光学来说,开发具有较大的第二波生成 (SHG) 特性的新材料至关重要.
- 含有d(0) 过渡金属和单对含有离子的材料是SHG应用的有希望的候选物.
研究的目的:
- 通过结合Nb(5+) 和酸离子来合成和表征一种新的SHG材料.
- 为了评估新材料的SHG性能,热稳定性和光学透明度.
主要方法:
- 的化学合成 BaNbO(IO(3))(5).
- 测量第二波生成 (SHG) 响应.
- 评估热稳定性和光学透明度.
主要成果:
- 一种新材料,BaNbO{}IO{}3)) {}5),已经成功地准备好.
- 该材料表现出非常大的SHG反应,大约是KH(2) PO(4) 的14倍和alpha-SiO(2) 的660倍.
- BaNbO ((IO ((3)) ((5) 是相匹配,热稳定,并具有广泛的透明区域.
结论:
- BaNbO ((IO ((3)) ((5) 是一个有前途的新材料,用于非线性光学应用,因为它有很大的SHG效应和有利的特性.
- 在设计高性能SHG材料时,Nb(5+) 和酸离子的组合是有效的.
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