竞争的磁性和超导性在Na(x) CoO2中,在半剂量注下
Manuel Bañobre-López1, Francisco Rivadulla, M Arturo López-Quintela
1Department of Physical Chemistry, University of Santiago de Compostela, 15782 Santiago de Compostela, Spain.
Journal of the American Chemical Society
|June 25, 2009
概括
在Na{0.5}CoO{2}中用替换会破坏磁波并诱导超导. 这一发现表明,超导性在特定的氧化状态附近出现,与磁相相竞争.
科学领域:
- 固态化学 固态化学
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 酸氧化物 (Na{x}CoO{2}) 具有复杂的磁性和电子性质.
- 半化Na(x) CoO(2) 具有旋转密度波 (SDW) 磁相的特征.
- 了解控制酸盐超导性的因素对于材料设计至关重要.
研究的目的:
- 研究热带离子交换对Na{0.5}CoO{2}的电子和磁性质的影响.
- 探索这个系统中磁性秩序和超导性之间的关系.
- 为了确定超导率与特定氧化状态的接近.
主要方法:
- 的拓性离子交换 (Na(+) 与H(3) O(+) 在Na(0.5) CoO(2) 中.
- 结构变化的表征,包括层间距离的修改.
- 分析的氧化状态和磁性特性.
主要成果:
- 离子的结合保持了恒定的氧化状态.
- 在H(3) O(+) 替换时,层间距离显著增加.
- 观察到旋转密度波的逐渐破坏.
- 在修改后的材料中成功诱导了超导.
结论:
- 通过以H(3) O(+) 取代Na(+) 的拓性取代,可以抑制磁性秩序,并诱导Na(0.5) CoO(2) 的超导性.
- 这个系统中的超导性似乎比以前估计的更接近1的Co3+/Co4+比.
- 超导的发展与磁相的形成直接竞争.
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