通过挫败的易斯对来复合氧化的复合
Edwin Otten1, Rebecca C Neu, Douglas W Stephan
1Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada, M5S 3H6.
Journal of the American Chemical Society
|July 3, 2009
概括
丧的易斯对有效地结合氧化,形成稳定的PNNOB链接. 这项研究详细介绍了这些新型化合物的合成,结构和结合.
科学领域:
- 有机金属化学 有机金属化学
- 无机化学 无机化学
背景情况:
- 丧的易斯对 (FLP) 是由于硬质阻碍而保持反应的易斯酸对.
- 氧化 (N2O) 是一种具有化学激活潜力的小分子.
研究的目的:
- 合成和描述由FLPs与氧化反应而形成的新化合物.
- 研究由此产生的PNNOB链接的结合和结构特征.
主要方法:
- 挫败的易斯对的合成使用无菌阻碍的素和 Lewis 酸.
- 使用光谱技术 (例如,NMR) 和X射线晶体学,对反应产品进行表征.
主要成果:
- 通过FLP成功结合氧化,产生完整的PNNOB链接.
- 对新物种进行了详细的结构和结合分析,证实了拟议的联系.
结论:
- 丧的易斯对为氧化的激活和稳定提供了可行的途径.
- 完整的PNNOB链接代表了有机金属化学中的新动机.
相关概念视频
Lewis Structures of Molecular Compounds and Polyatomic Ions
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
Resonance
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N-O and N=O bonds.
Formal Charges
In some cases, there are seemingly more than one valid Lewis structures for molecules and polyatomic ions. The concept of formal charges can be used to help predict the most appropriate Lewis structure when more than one reasonable structure exists.
Exceptions to the Octet Rule
Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
Resonance and Hybrid Structures
According to the theory of resonance, if two or more Lewis structures with the same arrangement of atoms can be written for a molecule, ion, or radical, the actual distribution of electrons is an average of that shown by the various Lewis structures.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
Lewis Symbols and the Octet Rule
Chemical bonds are complex interactions between two or more atoms or ions, which reduce the potential energy of the molecule. Gilbert N. Lewis developed a model called the Lewis model that simplified the depiction of chemical bond formation and provided straightforward explanations for the chemical bonds seen in most common compounds.


