碳基:SeBSe和SBS Pd (II) 复合物的合成和结构
Alexander M Spokoyny1, Matthew G Reuter, Charlotte L Stern
1Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
Journal of the American Chemical Society
|July 9, 2009
概括
研究人员使用m-carborane合成了新的丰富的钉复合物. 这些金属复合体具有独特的Pd-B(2) 键,代表了具有有趣电子特性的第一个金属钉结构.
科学领域:
- 有机金属化学 有机金属化学
- 化学 化学 化学
- 协调化学 协调化学
背景情况:
- 针复合体是协调化学中的多功能联结体.
- 碳酸,特别是m-碳酸,具有独特的电子和结构性质.
- 新型金属键的开发仍然是一个活跃的研究领域.
研究的目的:
- 报告新丰富的器复合物的合成.
- 探索涉及和的新型协调图案.
- 为了研究m-carborane所赋予的电子特性.
主要方法:
- 通过独立的路径合成SeBSe和SBS链体.
- 连接体与的金属化 (II).
- 由此产生的金属具复合物的特征.
主要成果:
- 成功合成来自m-carborane的独特,富含的钉复合物.
- 形成Pd-B(2) 键,通过或乙烯配体进行化.
- 展示了第一个金属具复合体的例子.
结论:
- 合成的复合物代表了一种新型的金属器化合物.
- 而m-carborane子显著影响这些复合物的电子性质.
- 这些发现为进一步探索含协调化合物开辟了道路.
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