在SmFeAsO系统中,兴奋剂诱导的超导性
Yong Liang Chen1, Cui Hua Cheng, Ya Jing Cui
1Key Laboratory of Advanced Technology of Materials (Ministry of Education of China), Superconductivity R&D Center (SRDC), Mail Stop 165, Southwest Jiaotong University, Chengdu, Sichuan 610031, China.
Journal of the American Chemical Society
|July 15, 2009
概括
在SmFeAsO中 (Ir) 兴奋剂会在16K时诱导超导.这种5D过渡金属兴奋剂会改变As-Fe-As键角,与充电储存层兴奋剂不同.
科学领域:
- 固态物理 固态物理
- 材料科学 材料科学 材料科学
- 超导电性 超导电性 超导电性
背景情况:
- 铁氧化物 (SmFeAsO) 是一种基于铁的超导体家族的母化合物.
- 了解兴奋剂效应对于调整超导特性至关重要.
研究的目的:
- 为了研究5d过渡金属伊 (Ir) 兴奋剂对SmFeAsO的影响.
- 探索超导的诱导及其与结构变化的相关性.
主要方法:
- 在SmFeAsO网格中以大约15个原子%的比例将 (Ir) 化学化.
- 结构分析以确定结合角度的变化,特别是As-Fe-As结合角度 (β).
主要成果:
- 在临界温度 (Tc) 为 16 K 的情况下,成功诱导了超导.
- 观察到由于Ir兴奋剂而导致As-Fe-As结合角度 (β) 的下降.
- 证明了Ir对β的兴奋剂的影响不同于对电荷储存层的兴奋剂.
结论:
- 用进行5d过渡金属注是一种有效的策略,可以诱导SmFeAsO的超导性.
- 观察到的结构变化 (β减小) 是诱导超导的关键因素.
- 兴奋剂部位显著影响结构反应和超导特性.
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