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Updated: Jun 20, 2026

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"点击"的聚合物刷与烯酸化学:室内和室外

Ryan M Hensarling1, Vanessa A Doughty, Justin W Chan

  • 1School of Polymers and High Performance Materials, University of Southern Mississippi, 118 College Drive #10076, Hattiesburg, Mississippi 39406, USA.

Journal of the American Chemical Society
|September 26, 2009
PubMed
概括

醇-亚尼点击化学为创建功能性表面提供了一种多功能方法. 这种方法可以在温和条件下快速地制造多组件表面,适合各种应用.

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Thiols are prepared using the hydrosulfide anion as a nucleophile in a nucleophilic substitution reaction with alkyl halides. For instance, bromobutane reacts with sodium hydrosulfide to give butanethiol.
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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...