压力下的重原子铁磁体:结构变化和磁反应
Masaki Mito1, Yuki Komorida, Hideki Tsuruda
1Faculty of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550 Japan.
Journal of the American Chemical Society
|October 23, 2009
概括
对铁磁材料施加物理压力可以改变它们的磁性. 增加的压力最初会增加铁磁秩序温度,但由于分子堆叠的变化,进一步的压缩会降低温度.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 有机电子 有机电子
背景情况:
- 铁磁有机材料为新的电子应用提供了潜力.
- 分子堆叠极大地影响了这些材料的磁性.
- 了解压力依赖性行为对于材料设计至关重要.
研究的目的:
- 为了研究物理压力对铁磁 bisdiselenazolyl 基的磁顺序的影响.
- 为了将pi-stack滑动的变化与铁磁排序温度 (T(C)) 相关联起来.
主要方法:
- 使用高达 1 GPa 的水静压.
- 在不同压力下测量铁磁调度温度 (T) (C).
- 对应施加压力的pi-stack滑动的分析.
主要成果:
- 物理压力减少了铁磁 bisdiselenazolyl 基中的 pi 堆滑动.
- 铁磁排序温度 (T(C)) 最初随着压力而增加,在1GPa附近达到21K的最大值.
- 在超过1GPa的压力下,随着pi-stack变得越来越叠加,T(C) 降低.
结论:
- 压力诱导的分子排列变化直接影响磁性排序温度.
- 优化压力是最大化这些有机材料铁磁性质的关键.
- 这项研究提供了有关有机基铁磁体的压力依赖磁性的见解.
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