可见光驱动的H2产生通过与染料敏感的TiO2纳米颗粒相连的化酶
Erwin Reisner1, Daniel J Powell, Christine Cavazza
1Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, United Kingdom.
Journal of the American Chemical Society
|November 26, 2009
概括
研究人员开发了一种混合纳米粒子系统,用于使用可见光生产 (H2). 通过特定的酶进行优化,在环境条件下实现高H2产量,在实际应用中显示出出色的稳定性.
科学领域:
- * 催化和纳米技术
- * 可再生能源生产
背景情况:
- * 开发高效的催化剂用于 (H2) 生产对于可再生能源至关重要.
- * 用酶修改的纳米粒子提供了利用光能产生H2的潜力.
研究的目的:
- *在环境条件下建立H2生产催化剂的性能标准.
- * 为了研究混合,酶修饰的纳米粒子用于可见光驱动的H2合成.
主要方法:
- *使用了来自Desulfomicrobium baculatum (Db [NiFeSe]-H) 的[NiFeSe]-酶的混合纳米粒子.
- * 固定Db [NiFeSe]-H到Ru染料敏感的TiO(2) 与三甲胺作为电子捐赠体.
- * 在可见光和环境条件下 (pH 7,25°C) 评估的H2产量.
主要成果:
- *优化的系统实现了约50 (mol H2) s(-1) (mol总酶) ((-1) 的周转频率.
- *即使在典型的太阳辐射水平下,也观察到高效的H2生产.
- * 在无氧和有氧条件下都表现出高的电催化稳定性.
结论:
- * 混合纳米粒子系统与Db [NiFeSe]-H是H2生产的熟练催化剂.
- * 该系统表现出适合板应用的强度.
- * 建立了在环境条件下运行的催化剂的潜在标准.
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