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Updated: Jun 16, 2026

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克莱森重新排列:从QM/MM模拟中了解溶剂效应和"在水上的"反应性

Orlando Acevedo1, Kira Armacost

  • 1Department of Chemistry and Biochemistry, Auburn University, Auburn, Alabama 36849, USA.

Journal of the American Chemical Society
|January 22, 2010
PubMed
概括

在"在水"环境中的反应显示,由于水通过键稳定极性过渡状态,其速度提高. 反应物的疏水替代剂通过将分子定向到水面来增强这种效果.

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