在无机纳米粒子和聚氧甲酸组件薄膜中的可逆光开关光
Bing Qin1, Hongyue Chen, Hui Liang
1National Center for Nanoscience and Technology, Beijing 100190, China.
Journal of the American Chemical Society
|February 17, 2010
概括
研究人员开发了一种具有光色特性的新型超薄膜. 这种无机混合材料显示可逆光切换,由紫外线或可见光控制,使新的光学应用成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 摄影化学的使用.
背景情况:
- 开发具有可调节光学特性的先进材料对于下一代电子和光子设备至关重要.
- 混合超薄膜由于不同材料组件的协同组合,提供了独特的优势.
- 光色材料在光照射时改变颜色或光学特性,具有显著的兴趣.
研究的目的:
- 准备和描述一种新的无机杂交超薄膜.
- 为了研究准备好的薄膜的光色和光切换行为.
- 了解观察到的光切换背后的机制.
主要方法:
- 用层层的组装技术来构建超薄膜.
- 该膜由Preyssler类型的多氧金属酸盐 (Na-POM) 和CdSe@CdS纳米粒子 (NP) 组成.
- 在紫外线和可见光照射下研究了光学特性,包括光和光色.
主要成果:
- 一种Na-POMs和CdSe@CdS NPs的新型无机杂交超薄膜已经成功准备好.
- 这部电影展示了可逆的光切换行为.
- 这种切换是通过交替的紫外线和可见光照射来控制的.
- 发光NP和光色Na-POM之间的光共振能量转移 (FRET) 被确定为潜在的机制.
结论:
- 这种新型无机杂交超薄膜具有可控制的可逆光切换.
- Na-POMs和FRET的光色性质是观察到光学行为的关键.
- 这种材料有可能用于光学开关,传感器和数据存储设备.
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