基于Fe的oxypnictide超导体的低温快速合成和超导性
Ai-Hua Fang1, Fu-Qiang Huang, Xiao-Ming Xie
1CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, PR China.
Journal of the American Chemical Society
|February 23, 2010
概括
研究人员开发了一种更快的合成方法,用于基于铁的oxypnictide超导体,达到超过50K的临界温度. 这种技术有效地结合了,增强了超导性并使高临界场成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 基于铁的氧尼克提德超导体表现出独特的电子特性.
- 以前的合成方法需要高温和长时间的反应时间.
- 加入像这样的挥发性兴奋剂是具有挑战性的,但对于增强超导性至关重要.
研究的目的:
- 开发一种更高效,更快速的合成路径,以Fe为基础的oxypnictide超导体.
- 研究一种新型合成方法对超导特性的影响.
- 在合成过程中优化挥发性兴奋剂 (如) 的保留.
主要方法:
- 利用不太稳定的前体化合物来增加反应的驱动力.
- 采用中介化合物的球磨.
- 在1173K进行短时间 (20分钟) 的合成反应.
主要成果:
- 实现了相纯的基于Fe的氧尼化超导体,其临界温度 (T(c)) 超过50K.
- 通过快速合成方法,证明成功地保留了,一种关键的兴奋剂.
- 在Sm{0.85) Nd{0.15) FeAsO{0.85) F{0.15) 中观察到大量超导和高上临界场高达392 T.
结论:
- 这种新的低温短时间合成方法对于生产高质量的基于Fe的氧基尼类超导体非常有效.
- 这种方法促进了挥发性兴奋剂的结合,从而提高了超导性能.
- 证明的高上临界场表明了在强磁场环境中应用的潜力.
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