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Ion-Exchange Membranes for the Fabrication of Reverse Electrodialysis Device
Published on: July 20, 2021
可调节的高性能交联性性离子交换膜用于燃料电池应用
Nicholas J Robertson1, Henry A Kostalik, Timothy J Clark
1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.
Journal of the American Chemical Society
|February 25, 2010
概括
新的交联性离子交换膜 (AAEMs) 通过环开放型转化聚合物合成. 这些膜具有高氧导电性和良好的机械性能,推动了燃料电池技术的发展.
科学领域:
- 聚合物化学 聚合物化学
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
背景情况:
- 燃料电池提供了有前途的能源转换,但需要改进的组件,以实现商业可行性.
- 聚合物电解质膜对于燃料电池性能至关重要,分离电极.
- 虽然已经建立了导质子膜,但导氧化膜 (性离子交换膜,AAEM) 的探索较少.
研究的目的:
- 开发用于性离子交换膜 (AAEM) 的新型交联膜材料.
- 为了提高燃料电池应用的氧化离子导电性和机械性能.
- 探索高级AAEM的简单合成方法.
主要方法:
- 使用环开元化聚合 (ROMP) 合成交联聚合物材料.
- 研究了合成膜的离子合并和导电性.
- 评估了由此产生的交联膜的机械性能.
主要成果:
- 通过ROMP.成功地生成了新的交叉连接膜材料.
- 在开发的AAEM中实现了高氧离子导电性.
- 具有良好的机械性能,适合燃料电池运行.
结论:
- 交叉连接增强了离子结合,导致AAEMs的高导电性.
- 简单的合成方法产生了具有和直接甲醇燃料电池潜力的材料.
- 开发的AAEM可以通过实现高效的性运行来显著推进燃料电池技术.
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