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Updated: Jun 14, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
09:58

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

一种高度调节的立体选择性olefination半稳定三基化物与N-sulfonyl imines

De-Jun Dong1, Hai-Hua Li, Shi-Kai Tian

  • 1Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China.

Journal of the American Chemical Society
|March 23, 2010
PubMed
概括

这项研究引入了一种新的维蒂格反应协议,使用N-硫尼尔胺而不是化物. 这种方法显著提高了基合成中的立体选择性,为Z-和E-基异构体实现了99:1以上的选择性.

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Preparation and Reactions of Sulfides

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Aldehydes and Ketones to Alkenes: Wittig Reaction Overview

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