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用装饰的单壁碳纳米管的氧化和随后的用减少

Ich C Tran1, Roberto Félix, Marcus Bär

  • 1Department of Chemistry, University of Nevada Las Vegas (UNLV), Las Vegas, Nevada 89154-4003, USA. citran@unlv.nevada.edu

Journal of the American Chemical Society
|April 2, 2010
PubMed
概括

单壁碳纳米管 (SWNTs) 上的 (Ti) 氧化,阻碍了的储存. (Li) 沉积减少了这种氧化,改善了Ti.

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The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.