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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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乙基脱酶反应机制的初步建模

Maciej Szaleniec1, Tomasz Borowski, Karola Schühle

  • 1Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Niezapominajek 8, 30-239 Krakow, Poland. ncszalen@cyf-kr.edu.pl

Journal of the American Chemical Society
|April 15, 2010
PubMed
概括

乙脱酶 (EBDH) 通过两种一电子转移机制催化乙氧化,涉及中间基和一个关键的胺残留物. 动态同位素效应揭示了pH取决于速度的决定性步骤和潜在的质子道.

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