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Updated: Jun 13, 2026

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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对铜催化乌尔曼型反应的机制和联体导向选择性的计算探索

Gavin O Jones1, Peng Liu, K N Houk

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|April 15, 2010
PubMed
概括

计算研究表明,联体选择决定了铜催化乌尔曼型合反应的选择性. 特定的配体会影响N-或O-arylation是否发生,主要是在烯化物激活阶段.

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